Quantization of the electromagnetic field

When an electromagnetic field is quantized, the field energy becomes discontinuous. After quantization, an electromagnetic (EM) field consist of discrete energy parcels, photons. Photons are massless particles of definite energy, definite momentum, and definite spin.

In order to explain the photoelectric effect, Einstein assumed heuristically in 1905 that an electromagnetic field consists of parcels of energy hν, where h is Planck's constant. In 1927 Paul A. M. Dirac was able to weave the photon concept into the fabrics of the new quantum mechanics and to describe the interaction of photons with matter. He applied a technique which is now generally called second quantization, although this term is somewhat of a misnomer for EM fields, because they are, after all, solutions of the classical Maxwell equations. In Dirac's theory the fields are quantized for the first time and it is also the first time that Planck's constant ℏ enters the expressions. In its original work, Dirac took the phases of the different EM waves ("modes") and the mode energies as dynamic variables to quantize (i.e., he reinterpreted them as operators plus commutation relations between them). At present it is more common to quantize the Fourier component of the vector potential. This is what will be done below.

Second quantization

Second quantization starts with an expansion of a scalar of vector field (or wave functions) in a basis consisting of a complete set of functions. These expansion functions depend on the coordinates of a single particle. The coefficients multiplying the basis functions are interpreted as operators and (anti)commutation relations between these new operators are imposed, commutation relations for bosons and anticommutation relations for fermions (nothing happens to the basis functions themselves). By doing this, the expanded field is converted into a fermion or boson operator field. The expansion coefficients have been promoted from ordinary numbers to operators, creation and annihilation operators. A creation operator creates a particle in the corresponding basis function and an annihilation operator annihilates a particle in this function.

In the case of EM fields the required expansion of the field is the Fourier expansion.

Electromagnetic field and vector potential

See here for more detail.

As the term suggests, an EM field consists of two vector fields, an electric field E(r,t) and a magnetic field B(r,t). Both are time-dependent vector fields that in vacuum depend on a third vector field A(r,t) (the vector potential) through

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \begin{align} \mathbf{B}(\mathbf{r}, t) &= \boldsymbol{\nabla}\times \mathbf{A}(\mathbf{r}, t)\\ \mathbf{E}(\mathbf{r}, t) &= - \frac{\partial \mathbf{A}(\mathbf{r}, t)}{\partial t}. \\ \end{align} }

The Fourier expansion of the vector potential enclosed in a finite box of volume V is

$\mathbf {A} (\mathbf {r} ,t)=\sum _{\mathbf {k} }\sum _{\mu =-1,1}\left(\mathbf {e} ^{(\mu )}(\mathbf {k} )a_{\mathbf {k} }^{(\mu )}(t)\,e^{i\mathbf {k} \cdot \mathbf {r} }+{\bar {\mathbf {e} }}^{(\mu )}(\mathbf {k} ){\bar {a}}_{\mathbf {k} }^{(\mu )}(t)\,e^{-i\mathbf {k} \cdot \mathbf {r} }\right),$

where the wave vector k gives the propagation direction of A(r,t); the length of the wave vector is |k| = 2πν/c = ω/c, with ν the frequency of the mode (Fourier component) and c is the speed of light. The two perpendicular unit vectors e^(μ) ("polarization vectors") are perpendicular to k. The k-component of A (a vector perpendicular to k) lies in the plane spanned by e⁽¹⁾ and e⁽⁻¹⁾. The Fourier coefficients $a_{\mathbf {k} }^{(\mu )}(t),\;{\bar {a}}_{\mathbf {k} }^{(\mu )}(t)$ can be seen as the variables defining the vector potential, in the following they will be promoted to operators.

Quantization of EM field

The best known example of quantization is the replacement of the time-dependent linear momentum of a particle by the rule

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \mathbf{p}(t) \rightarrow -i\hbar\boldsymbol{\nabla}} .

Note that Planck's constant is introduced here and that the time-dependence of the classical expression is not taken over in the quantum mechanical operator (this is true in the so-called Schrödinger picture).

For the EM field we do something similar and apply the quantization rules:

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \begin{align} a^{(\mu)}_\mathbf{k}(t)\, &\rightarrow\, \sqrt{\frac{\hbar}{2 \omega V\epsilon_0}}\, a^{(\mu)}(\mathbf{k}) \\ \bar{a}^{(\mu)}_\mathbf{k}(t)\, &\rightarrow\, \sqrt{\frac{\hbar}{2 \omega V\epsilon_0}}\, {a^\dagger}^{(\mu)}(\mathbf{k}) \\ \end{align} }

subject to the boson commutation relations

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \begin{align} \big[ a^{(\mu)}(\mathbf{k}),\, a^{(\mu')}(\mathbf{k}') \big] & = 0 \\ \big[{a^\dagger}^{(\mu)}(\mathbf{k}),\, {a^\dagger}^{(\mu')}(\mathbf{k}')\big] &=0 \\ \big[a^{(\mu)}(\mathbf{k}),\,{a^\dagger}^{(\mu')}(\mathbf{k}')\big]&= \delta_{\mathbf{k},\mathbf{k}'} \delta_{\mu,\mu'}. \end{align} }

The square brackets indicate a commutator, defined by

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \big[ A, B\big] \equiv AB - BA }

for any two quantum mechanical operators A and B.

The quantized fields (operator fields) are the following

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \begin{align} \mathbf{A}(\mathbf{r}) &= \sum_{\mathbf{k},\mu} \sqrt{\frac{\hbar}{2 \omega V\epsilon_0}} \left(\mathbf{e}^{(\mu)} a^{(\mu)}(\mathbf{k}) e^{i\mathbf{k}\cdot\mathbf{r}} + \bar{\mathbf{e}}^{(\mu)} {a^\dagger}^{(\mu)}(\mathbf{k}) e^{-i\mathbf{k}\cdot\mathbf{r}} \right) \\ \mathbf{E}(\mathbf{r}) &= i\sum_{\mathbf{k},\mu} \sqrt{\frac{\hbar\omega}{2 V\epsilon_0}} \left(\mathbf{e}^{(\mu)} a^{(\mu)}(\mathbf{k}) e^{i\mathbf{k}\cdot\mathbf{r}} - \bar{\mathbf{e}}^{(\mu)} {a^\dagger}^{(\mu)}(\mathbf{k}) e^{-i\mathbf{k}\cdot\mathbf{r}} \right) \\ \mathbf{B}(\mathbf{r}) &= i\sum_{\mathbf{k},\mu} \sqrt{\frac{\hbar}{2 \omega V\epsilon_0}} \left((\mathbf{k}\times\mathbf{e}^{(\mu)}) a^{(\mu)}(\mathbf{k}) e^{i\mathbf{k}\cdot\mathbf{r}} - (\mathbf{k}\times\bar{\mathbf{e}}^{(\mu)}) {a^\dagger}^{(\mu)}(\mathbf{k}) e^{-i\mathbf{k}\cdot\mathbf{r}} \right), \\ \end{align} }

where ω = c |k| = ck.

Hamiltonian of the field

Substitution of the operators into the classical Hamiltonian gives the Hamilton operator of the EM field

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \begin{align} H &= \frac{1}{2}\sum_{\mathbf{k},\mu=-1,1} \hbar \omega \Big({a^\dagger}^{(\mu)}(\mathbf{k})\,a^{(\mu)}(\mathbf{k}) + a^{(\mu)}(\mathbf{k})\,{a^\dagger}^{(\mu)}(\mathbf{k})\Big) \\ &= \sum_{\mathbf{k},\mu} \hbar \omega \Big({a^\dagger}^{(\mu)}(\mathbf{k})a^{(\mu)}(\mathbf{k}) + \frac{1}{2}\Big) \end{align} }

By the use of the commutation relations the second line follows from the first. Note that ℏω = h ν = ℏ c |k|, which is the well-known Einstein expression for photon energy. Remember that ω depends on k, even though it is not explicit in the notation. The notation ω(k) could have been introduced, but is not common.

Digression: harmonic oscillator

The second quantized treatment of the one-dimensional quantum harmonic oscillator is a well-known topic in quantum mechanical courses. We digress and say a few words about it. The harmonic oscillator Hamiltonian has the form

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle H = \hbar \omega \big( a^\dagger a + \tfrac{1}{2} \big) }

where ω ≡ 2πν is the fundamental frequency of the oscillator. The ground state of the oscillator is designated by | 0 ⟩ and is referred to as vacuum state. It can be shown that Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \scriptstyle a^\dagger} is an excitation operator, it excites from an n fold excited state to an n+1 fold excited state:

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle a^\dagger |n \rangle = |n+1 \rangle \sqrt{n+1} \quad\hbox{in particular}\quad a^\dagger |0 \rangle = |1 \rangle \quad\hbox{and}\quad (a^\dagger)^n |0\rangle \propto |n\rangle. }

Since harmonic oscillator energies are equidistant, the n-fold excited state | n⟩ can be looked upon as a single state containing n particles (sometimes called vibrons) all of energy hν. These particles are bosons. For obvious reason the excitation operator Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle a^\dagger} is called a creation operator.

From the commutation relation follows that the Hermitian adjoint Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \, a} de-excites:

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle a |n \rangle = |n-1 \rangle \sqrt{n} \quad\hbox{in particular}\quad a |0 \rangle \propto 0 \rightarrow a |0 \rangle = 0, }

because a function times the number 0 is the zero function. For obvious reason the de-excitation operator Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \,a} is called an annihilation operator.

Suppose now we have a number of non-interacting (independent) one-dimensional harmonic oscillators, each with its own fundamental frequency ω_i. Because the oscillators are independent, the Hamiltonian is a simple sum:

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle H = \sum_i \hbar\omega_i \Big(a^\dagger(i) a(i) +\tfrac{1}{2} \Big). }

Making the substitution

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle i \rightarrow (\mathbf{k}, \mu) }

we see that the Hamiltonian of the EM field can be looked upon as a Hamiltonian of independent oscillators of energy ω = |k| c and oscillating along direction e^(μ) with μ=1,−1.

Photon energy

The quantized EM field has a vacuum (no photons) state | 0 ⟩. The application of, say,

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \big( {a^\dagger}^{(\mu)}(\mathbf{k}) \big)^m \, \big( {a^\dagger}^{(\mu')}(\mathbf{k}') \big)^n \, |0\rangle \propto \Big| m^{(\mu)}(\mathbf{k}), \, n^{(\mu')}(\mathbf{k}') \, \Big\rangle, }

gives a quantum state of m photons in mode (μ, k) and n photons in mode (μ', k'). We use the proportionality symbol because the state on the right-hand is not normalized to unity.

We can shift the zero of energy and rewrite the Hamiltonian as

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle H= \sum_{\mathbf{k},\mu} \hbar \omega N^{(\mu)}(\mathbf{k}) \quad\hbox{with}\quad N^{(\mu)}(\mathbf{k}) \equiv {a^\dagger}^{(\mu)}(\mathbf{k})a^{(\mu)}(\mathbf{k}) }

The operator Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle N^{(\mu)}(\mathbf{k})} is the number operator. When acting on a quantum mechanical photon state, it returns the number of photons in mode (μ, k). Such a photon state is an eigenstate of the number operator. This is why the formalism described here, is often referred to as the occupation number representation. The effect of H on a single-photon state is

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle H \left({a^\dagger}^{(\mu)}(\mathbf{k}) \,|0\rangle\right) = \hbar\omega \left( {a^\dagger}^{(\mu)}(\mathbf{k}) \,|0\rangle\right). }

Apparently, the single-photon state is an eigenstate of H and Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \hbar \omega = h \nu } is the corresponding energy.

Example photon density

In this article the electromagnetic energy density was computed that a 100kW radio station creates in its environment; at 5 km from the station it was estimated to be 2.1·10⁻¹⁰ J/m³. Is quantum mechanics needed to describe the broadcasting of this station?

The classical approximation to EM radiation is good when the number of photons is much larger than unity in the volume

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \left(\frac{\lambda}{2\pi}\right)^3 , }

where λ is the length of the radio waves. In that case quantum fluctuations are negligible and cannot be heard.

Suppose the radio station broadcasts at ν = 100 MHz, then it is sending out photons with an energy content of νh = 1·10⁸× 6.6·10⁻³⁴ = 6.6·10⁻²⁶ J, where h is Planck's constant. The wavelength of the station is λ = c/ν = 3 m, so that λ/(2π) = 48 cm and the volume is 0.111 m³. The energy content of this volume element is 2.1·10⁻¹⁰ × 0.111 = 2.3 ·10⁻¹¹ J, which amounts to

3.5 ·10¹² photons per Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \left (\frac{\lambda}{2\pi}\right)^3}

Obviously, 3.5 ·10¹² is much larger than one and hence quantum effects do not play a role; the waves emitted by this station are well into the classical limit, even when it plays non-classical music, for instance of Led Zepplin.

Photon momentum

Introducing the operator expansions for E and B into the classical form

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \mathbf{P}_\textrm{EM} = \epsilon_0 \iiint_V \mathbf{E}(\mathbf{r},t)\times \mathbf{B}(\mathbf{r},t)\, \textrm{d}^3\mathbf{r}, }

yields

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \mathbf{P}_\textrm{EM} = \sum_{\mathbf{k},\mu} \hbar \mathbf{k} \Big({a^\dagger}^{(\mu)}(\mathbf{k})a^{(\mu)}(\mathbf{k}) + \frac{1}{2}\Big) = \sum_{\mathbf{k},\mu} \hbar \mathbf{k} N^{(\mu)}(\mathbf{k}). }

The 1/2 that appears can be dropped because when we sum over the allowed k, k cancels with −k. The effect of P_EM on a single-photon state is

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \mathbf{P}_\textrm{EM} \left({a^\dagger}^{(\mu)}(\mathbf{k}) \,|0\rangle \right) = \hbar\mathbf{k} \left( {a^\dagger}^{(\mu)}(\mathbf{k}) \,|0\rangle\right). }

Apparently, the single-photon state is an eigenstate of the momentum operator, and Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \hbar \mathbf{k}} is the eigenvalue (the momentum of a single photon).

Photon mass

The photon having non-zero linear momentum, one could imagine that it has a non-vanishing rest mass m₀, which is its mass at zero speed. However, we will now show that this is not the case: m₀ = 0.

Since the photon propagates with the speed of light, special relativity is called for. The relativistic expressions for energy and momentum squared are,

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle E^2 = \frac{m_0^2 c^4}{1-v^2/c^2}, \quad p^2 = \frac{m_0^2 v^2}{1-v^2/c^2}. }

From p²/E²,

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \frac{v^2}{c^2} = \frac{c^2p^2}{E^2} \quad\Longrightarrow\quad E^2= \frac{m_0^2c^4}{1 - c^2p^2/E^2} \quad\Longrightarrow\quad m_0^2 c^4 = E^2 - c^2p^2. }

Use

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle E^2 = \hbar^2 \omega^2\quad\mathrm{and}\quad p^2 = \hbar^2 k^2 = \frac{\hbar^2 \omega^2}{c^2} }

and it follows that

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle m_0^2 c^4 = E^2 - c^2p^2 = \hbar^2 \omega^2 - c^2 \frac{\hbar^2 \omega^2}{c^2} = 0, }

so that m₀ = 0.

Photon spin

The photon can be assigned a triplet spin with spin quantum number S = 1. This is similar to, say, the nuclear spin of the ¹⁴N isotope, but with the important difference that the state with M_S = 0 is zero, only the states with M_S = ±1 are non-zero.

We define spin operators:

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle S_z \equiv -i\hbar\Big( \mathbf{e}_{x} \mathbf{e}_{y} - \mathbf{e}_{y} \mathbf{e}_{x}\Big) \quad\hbox{and cyclically}\quad x\rightarrow y \rightarrow z \rightarrow x. }

The products between the unit vectors on the right-hand side are dyadic products. The unit vectors are perpendicular to the propagation direction k (the direction of the z axis, which is the spin quantization axis).

The spin operators satisfy the usual angular momentum commutation relations

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle [S_x, \, S_y] = i \hbar S_z \quad\hbox{and cyclically}\quad x\rightarrow y \rightarrow z \rightarrow x. }

Indeed,

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle [S_x, \, S_y] = -\hbar^2 \Big( \mathbf{e}_{y} \mathbf{e}_{z} - \mathbf{e}_{z} \mathbf{e}_{y}\Big) \cdot \Big( \mathbf{e}_{z} \mathbf{e}_{x} - \mathbf{e}_{x} \mathbf{e}_{z}\Big) + \hbar^2 \Big( \mathbf{e}_{z} \mathbf{e}_{x} - \mathbf{e}_{x} \mathbf{e}_{z}\Big) \cdot \Big( \mathbf{e}_{y} \mathbf{e}_{z} - \mathbf{e}_{z} \mathbf{e}_{y}\Big) = i\hbar \Big[ -i\hbar \big(\mathbf{e}_{x} \mathbf{e}_{y} - \mathbf{e}_{y} \mathbf{e}_{x}\big)\Big] =i\hbar S_z. }

Define states

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle | \mathbf{k}, \mu \rangle \equiv {a^\dagger}^{(\mu)}(\mathbf{k}) \,|0\rangle \leftrightarrow \mathbf{e}^{(\mu)} e^{i\mathbf{k}\cdot \mathbf{r}}. }

By inspection it follows that

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle -i\hbar\Big( \mathbf{e}_{x} \mathbf{e}_{y} - \mathbf{e}_{y} \mathbf{e}_{x}\Big)\cdot \mathbf{e^{(\mu)}} = \mu \mathbf{e}^{(\mu)}, \quad \mu=1,-1, }

and correspondingly we see that μ labels the photon spin,

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle S_z | \mathbf{k}, \mu \rangle = \mu | \mathbf{k}, \mu \rangle,\quad \mu=1,-1. }

Because the vector potential A is a transverse field, the photon has no forward (μ = 0) spin component.