Michael Faraday

Michael Faraday (22 September 1791 – 25 August 1867) was an English physicist and chemist. In 1821, soon after Oersted's discovery, he published his work on—what he called—electromagnetic rotation (the principle behind the electric motor). In 1831, Faraday discovered electromagnetic induction, the principle behind the electric transformer and electric generator. In chemistry Faraday discovered benzene, contributed importantly to electrochemistry, and popularized terminology such as anode, cathode, electrode, and ion.

Biography

The Faraday family came from the North of England. Before Michael was born, his father, a blacksmith, took his wife and two small children south, in search of work. The family settled briefly in Newington Butts, which was then a separate village but is now part of Southwark, a borough in South London, where Michael was born. Soon the family moved into London itself. Michael's father had poor health (he died in 1810) and Michael grew up in poverty. The family was close and obtained strength from their orthodox faith, Sandemanian, a splitoff from the Presbyterian church. Michael would stay faithful to his religion for the rest of his life.

At fourteen Michael became an apprentice at a bookseller and bookbinder's shop and moved in with his boss's family. In this household were plenty of books around for Michael to read. For instance the third edition of Encyclopedia Brittanica was one of the shop's bookbinding assignments. His fascination for electricity was first stirred by reading the encyclopedia article about it. From a customer of the shop Faraday, twenty-one and nearing the end of his apprenticeship, received tickets for a series of four lectures on chemistry delivered by Sir Humphry Davy at the Royal Institution. These lectures, in the spring of 1812, were recorded by Faraday in careful lecture notes and neatly bound by him as a book.

In the fall of 1812 Michael was a fully-qualified bookbinder and moved to another firm. Faraday didn't particularly like his new job, but within a few weeks his life took a sudden turn. Davy needed help for a few days from somebody with a little knowledge of chemistry and Faraday got the job, probably by a good word from another customer of his earlier boss. Faraday showed his lecture notes to Davy, who must have been pleased by so much attention to his words. After the temporary job ended, Faraday had to leave the Royal Institution as there was no money to continue his position. However, as luck would have it, not much later Humphry Davy's laboratory assistant was fired because of a drinking problem and his position became vacant. Not surprisingly, Faraday got the job and started on 1 March 1813 at the Royal Institution where he would stay for fifty-two years, until 1865.

Half a year later, Faraday was invited by Sir Davy to accompany him and Lady Davy on a tour of Europe. Davy was a renowned "natural philosopher" (later the name "scientist" was coined for this profession by Whewell) and had entry to many scientific circles on the continent. Michael accepted the invitation, but during the tour sometimes regretted this, because Lady Davy, who is known to have been very snobbish, treated him as a lowly servant. Professionally, the tour was a great success for Faraday, though, because he had the chance to converse with many of the leading scientists in France, Switzerland and Italy. He saw he Alps and the Mediterranean, learned French and Italian, and became Davy's collaborator, not just his assistant. The chemist John Hall Gladstone (1827–1902), who knew Faraday well, wrote:

This year and a half may be considered as the time of Faraday's education; it was the period of his life that best corresponds with the collegiate course of other men who have attained high distinction in the world of thought. But his University was Europe; his professors the master whom he served, and those illustrious men to whom the renown of Davy introduced the travelers".

Faraday's improved abilities were recognized upon his return at the Royal Institution. He was promoted to superintendent of the apparatus and got better rooms (he was living at the top of the Royal Institution building in Albemarle Street). Until early 1820 Faraday's work was mostly in chemistry and he earned an international reputation as a good, solid chemist, but not yet a brilliant one. His reputation as a chemist got an enormous boost when he managed to liquify chlorine (1823) and discovered benzene (1825).

In physics, he discovered that a steady direct electric current can move a magnet in circles (see the section below on electromagnetic rotation). This discovery, made in the second half of 1821, is the basis of the electric motor. It gave Faraday instantaneous world fame. On the other hand, the discovery estranged him from Davy, who was of the opinion that Faraday plagiarized the idea from William Wollaston. In April 1821, Wollaston, after hearing of Oersted's discovery, visited the Royal Institution and tried, in collaboration with Davy, in vain something similar that Faraday managed to do do later the same year. When Faraday became Fellow of the Royal Society in 1824, he had one vote against him and it is believed that this was Davy's. If this is so, Wollaston must have voted in favor of Faraday and must have forgiven him the alleged plagiarism.

Also in 1821, on June 12, Faraday married Sarah Barnard, another Sandemanian and the couple lived together "above the shop" at the top of the Royal Instute building until 1862. The couple never had children. Sarah was a steadying influence in Michael's life. She was a warm and charming person filled with maternal feelings which, in the absence of children, she lavished upon her husband and her nieces.

In 1825 Faraday succeeded Davy as director of the Royal Institution (RI) and, beginning in 1826, he revived the tradition of popular lectures at the RI, many given by himself. For many years he, and others, delivered around Christmas a short lecture series especially for children. These attracted an audience from the upper social classes of London. The most famous (1848) of the Christmas lecture series, called The Chemical History of a Candle, was published and has gone through innumerable editions in many languages. Another well-known series directed to young persons is about various forces in nature (1859). In 1833 Faraday was honored by a Fullerian professorship of chemistry at the RI; the chair was especially instated for him and still exists today.

In 1831 Faraday discovered—what he called—electromagnetic induction, which is the effect that a moving magnet can induce an electric current in a wire (see below). During the following years Faraday developed the idea of electric and magnetic force lines, (later called fields by William Thomson, Lord Kelvin) a concept that contradicts instantaneous action at a distance. Because of his background, Faraday hardly knew any mathematics, his intuitive ideas were qualitative and non-mathematical. Most of the contemporary physicists, who generally were well versed in the mathematical formulation of Sir Isaac Newton's mechanics in which action at a distance plays an important role, frowned upon Faraday's ideas. However, at the and of Faraday's life his ideas were cast into a beautiful mathematical form by James Clerk Maxwell. Maxwell's equations are today still the accepted basis of the theory of electromagnetism; they show that visible light is an electromagnetic wave, just as radio waves, microwaves, infrared and gamma radiation.

Faraday was strong physically, but suffered occasionally from headaches, memory lapses, and bouts of depression. These symptoms increased in severity and frequency until, in 1840, at age forty-nine, Faraday had a major nervous breakdown. For four years he was hardly able to work. However, in 1845 he had recovered and started his research activities again. Because he believed strongly in the unity of forces, he investigated the effect of a magnetic field on light and found, in 1845, that the polarization plane of polarized light is rotated by such a field; this is the Faraday effect.

True to his Sandemanian principles, Faraday turned down the offer of a knighthood, and twice declined to become president of the Royal Society. When he was seventy years old in 1861, he resigned from the RI, but he was asked to stay on in a nominal post, which he did until 1865. In 1862 he and Sarah moved out from Albemarle Street into a house provided by Queen Victoria at the suggestion of Prince Albert. He died there on 25 August 1867.

Faraday's science

Electromagnetic rotation

PD Image
Adaptation of Faraday's illustration of his apparatus for electromagnetic rotation. The vessels are filled with mercury (grey), current runs through copper wires (red) and the bar magnets, floating on the left and fixed on the right, are blue.

When Faraday heard of Oersted's discovery (1820) that a steady electric current in a wire generates a circular magnetic field (with the current-carrying wire the center of the field), it occurred to him that a magnetic pole would be pushed around a circle by such a field and hence would rotate forever, or at least as long as the current is running. In 1821 he designed the apparatus shown in the figure on the right. In the vessel on the left a strong bar magnet floats in mercury held in place only by a thread at its bottom. Recall that mercury is a heavy liquid that is a very good conductor of electricity. A fixed cupper wire is dipped into the mercury. At the bottom of the vessel a wire sticks into the mercury. In the vessel on the right a bar magnet is fixed in a conducting (copper) socket that extends into the bath and a copper wire that hangs from a kind of ball bearing is dipped into the mercury. When a direct current is switched on (running through the wires and the mercury baths) the wire on the right rotates around the magnet so fast that—as described by Faraday—the eye can scarcely follow the motion. The magnet on the left rotates around the fixed wire. Note that Faraday's setup is such that only one pole of the two poles of the magnets is involved. If the magnets are turned around (i.e., the North and South poles are interchanged) the rotation of the wire and the magnet changes direction. The same happens if the current runs in opposite direction. Faraday, who coined the term electromagnetic rotation for this effect, had in fact invented the electric motor.

Electromagnetic induction

Faraday's equipment with which he discovered electromagnetic induction. From Ref.

In a series of experiments published in 1831, Faraday, knowing that electricity influences magnetism, investigated whether the converse effect is also true, or in other words, whether magnetism has an effect on an electric current. He took two coils of insulated wire wound around a soft iron ring of six inches in external diameter. (See the figure on the left). The ring itself was 7/8 inch thick. The coils were not connected to each other. The coil A on the right-hand side was hooked onto a battery, and a copper wire attached to the coil B passed three feet away from the ring just over a magnetic needle. At the moment the battery was connected to coil A and a current started to run, the needle oscillated and settled after a while in its original position. On breaking the battery connection, again a disturbance of the needle was observed. When Faraday performed this experiment, it was already known that the part of the iron ring covered by coil A becomes a magnet—an electromagnet—when current runs through the coil. The magnetic North and South pole are at the beginning and the end of coil A—it depends on the direction of the current what we call North or South—and hence coil B is wound around a magnet, too, as long as the current is running. Faraday had now discovered that the changes in the strength of the magnet, which occur when switching the current on and off, give a current in the wire connected to coil B, which, we reiterate, is not in electric contact with A. It was certain that a current was running through B because it was known by Oersted's discovery that a current moves a magnetic needle. Faraday was fascinated by the symmetry he had discovered: a moving electric charge (a current) gives a magnetic field and a magnet varying in strength induces an electric current. He called this effect electromagnetic induction. Later he extended the experiment by moving a permanent cylindrical magnet in and out a coil observing an electric current in the coil induced by the moving magnet. It is worthy of note that the effect is of extreme importance in modern society, because it is magnetic induction that is at the basis of electric generators and voltage transformers.

Chemistry

To the displeasure of his boss Humphry Davy, Faraday managed to liquify chlorine in 1823. Davy felt that he deserved credit for this discovery, since he had suggested the problem to his coworker. It is likely that this feeling of displeasure was one of the reasons that Davy later objected to Faraday becoming fellow of the Royal Society. In 1825 Faraday discovered benzene, which he called bicarburet of hydrogen. He isolated it from a liquid obtained in the production of oil gas. At the same time he did research on glass that, however, did not have much result; but he found the recipe for heavy glass. Around 1845 Faraday discovered that the polarization of light by different kinds of glass, among which heavy glass, is affected by a magnetic field. This rotation of the polarization plane of light by a magnetic field, is now known as the Faraday effect.

In the 1830s Faraday did very important work in electrochemistry and formulated two laws that now carry his name. The basic setup of electrochemistry is simple: it consists of a vessel containing an electrolyte, which is a solution of charged particles (ions). Since this solution is neutral in total, the total charge carried by the positive particles (cations) is he same (in absolute value) as the total charge carried by the negative particles (anions). Two electrodes are dipped into the electrolyte. Outside the vessel a direct current (DC) runs from the negatively charged electrode (the cathode) to the positively charged electrode (the anode). Inside the vessel cations move to the cathode, pick up electrons—which carry negative charge—so that the cations are neutralized and are deposited on the cathode (or if the neutral species is gaseous, it escapes from the cathode in the form of gas). At the anode the opposite happens: anions lose their excess electrons and are deposited. Outside the vessel the electrons run from the anode to the cathode (by definition they run in direction opposite to the DC). Faraday's first law states that the amount of substance deposited on the electrodes is proportional to the amount of current that passed through the electrodes. In the case of a steady current this amount is equal to the time that the current has been running multiplied by the strength of the current. A constant proportional to this amount is called after Faraday—Faraday's constant. Faraday's second law of electrochemistry is a recognition of the fact that anions and cations may carry one, two, three, etc. elementary charges, so that it takes one, two, three, etc., electrons, respectively, to neutralize the cation, while the anion must lose one, two, three, etc. electron to become neutral. These differently charged ions will all give the deposition of one atom only, so that, e.g., twice as much electricity is needed to generate an atom from a doubly charged ion as from a singly charged ion. Faraday was the first to see these facts clearly, moreover, he introduced the corresponding terminology (electrolyte, electrode, anode, cathode, ion, anion, and cation) derived from old Greek, helped by his friend William Whewell of Trinity College, Cambridge, who knew Greek.

Bibliography

• Anderson, Ronald. "The Crafting of Scientific Meaning and Identity: Exploring the Performative Dimensions of Michael Faraday's Texts," Perspectives on Science" - Volume 14, Number 1, Spring 2006, pp. 7-39 in Project Muse
• Bence Jones, Henry. The Life and Letters of Faraday, (2 vol. 1870, reprint 2006) online first edition
• Cantor, Geoffrey. Michael Faraday: Sandemanian and Scientist. (1991)
• Cantor, G. N., D. Gooding, and F. A. J. L. James. Faraday (1991); rev. edn as Michael Faraday (1996)
• Cropper, William H. Great Physicists: The life and times of leading physicists from Galileo to Hawking, Oxford University Press, Oxford (2001)
• Gooding, D., and F. A. J. L. James, eds. Faraday rediscovered: essays on the life and work of Michael Faraday, 1791–1867 (1985)
• Gribbin, J. The Scientists, A History of Science Told Through the Lives of Its Greatest Inventors, Random House, New York, 2002. Paperback edition (2004) pp. 412-424.
• James, Frank A. J. L. "Faraday, Michael (1791–1867)", Oxford Dictionary of National Biography, (2004); online edition, Jan 2008 at OUP
• Jensen, William B. "Michael Faraday and the Art and Science of Chemical Manipulation." Bulletin for the History of Chemistry (1991) (No. 11): 65–76
• Romo, Jose, and Manuel Doncel. "Faraday's initial mistake concerning the direction of induced currents." Archive for History of Exact Sciences 1994. 47: 291–385.
• Steinle, Friedrich. "Work, Finish, Publish? The formation of the second series of Faraday's 'Experimental researches in electricity.'" Physis, 1996. 33: 141–220.
• Tweney, Ryan D. . "Faraday's notebooks: The active organization of creative science." Physics Education. 1991 26: 301–306.
• Tweney, Ryan D. "Discovering Discovery: How Faraday Found the First Metallic Colloid," Perspectives on Science Volume 14, Number 1, Spring 2006, pp. 97-121 in Project Muse
• Tweney, Ryan D. "Stopping Time: Faraday and the Scientific Creation of Perceptual Order." Physis 1992. 29: 149–164.
• Tyndall, John. Faraday as a Discoverer. (1873) online edition
• Williams, L. Pearce "Michael Faraday, a biography" New York, Basic Books (1965)

Primary sources

• Faraday, Michael. Experimental Researches in Electricity (1855) online edition
• Faraday, Michael. The Chemical History Of A Candle (1908) online edition
• Faraday, Michael. Experimental Researches in Chemistry and Physics, (1859) 496 pages; online edition
• Faraday, Michael. The Correspondence of Michael Faraday. edited by Frank A.J.L. James. Volume 1: 1811—1831; Volume 2: 1832–1840; Volume 3: 1841–1848. Volume 4: 1849–1855 (1991–1996)
• Martin, Thomas, ed. Faraday's Diary: Being the Various Philosophical Notes of Experimental Investigation Made by Michael Faraday During the Years 1820–1862 (8 vol 1932-36).