Flue gas: Difference between revisions

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'''Flue gas''' is [[gas]] that exits to the atmosphere via a ''flue'' which may be a pipe, channel or chimney for conveying [[combustion]] product gases from a fireplace, oven, [[furnace]], [[boiler]] or [[steam generator]].
'''Flue gas''' is [[gas]] that exits to the atmosphere via a ''flue'' which may be a pipe, channel or chimney for conveying [[combustion]] product gases from a fireplace, oven, [[furnace]], [[boiler]] or [[steam generator]].


Flue gases are produced when [[coal]], [[fuel oil]], [[natural gas]], [[wood]] or any other fuel is [[combustion|combusted]] in an industrial [[furnace]] or [[boiler]], a [[steam-generator]] in a   [[fossil fuel]] [[power plant]] or other combustion sources.
Flue gases are produced when [[coal]], [[fuel oil]], [[natural gas]], [[wood]] or any other fuel is [[combustion|combusted]] in an industrial [[furnace]] or [[boiler]], a steam generator in a [[fossil fuel]] [[power plant]] or other combustion sources.


== Flue gas composition ==
== Flue gas composition ==
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Flue gas is usually composed of [[carbon dioxide]] (CO<sub>2</sub>) and water vapor as well as [[nitrogen]] and excess [[oxygen]] remaining from the intake combustion air. It may also contain a small percentage of air pollutants such as [[particulate matter]], [[carbon monoxide]], [[nitrogen oxide]]s, [[sulfur oxide]]s and [[mercury]]. Typically, more than two-thirds of the flue gas is nitrogen.
Flue gas is usually composed of [[carbon dioxide]] (CO<sub>2</sub>) and water vapor as well as [[nitrogen]] and excess [[oxygen]] remaining from the intake combustion air. It may also contain a small percentage of air pollutants such as [[particulate matter]], [[carbon monoxide]], [[nitrogen oxide]]s, [[sulfur oxide]]s and [[mercury]]. Typically, more than two-thirds of the flue gas is nitrogen.


Table 1 provides the amounts of flue gas (on a dry basis as well as a wet basis) that are generated by burning a typical flue gas or  fuel oil or coal. The flue gas amounts were obtained by [[stoichiometry|stoichiometric]] calculations using the indicated typical excess combustion air percentages:  
The table below provides the amounts of flue gas (on a dry basis as well as a wet basis) that are generated by burning a typical fuel gas, fuel oil or coal. The flue gas amounts were obtained by [[stoichiometry|stoichiometric]] calculations using the indicated typical excess combustion air percentages:<br>
 
{{Image|FossilFuelFlueGas.png|left|525px}}{{clear}}  
{| class="wikitable" align=center
Given the amount of gas, oil or coal fuel burned in a combustion device, then the flue gas generation data (i.e., m³/GJ of fuel) in the above table provides a basis for estimating the amount of flue gas generated.
|-
|+ Table 1: Flue gas generated by burning fossil fuels
! Combustion data!!Fuel gas!!Fuel oil!!Coal
|-
|'''Fuel properties:'''||&nbsp;||&nbsp;||&nbsp;
|-
|Gross [[heating value]], MJ/m³||align=center|43.01||&nbsp;||&nbsp;
|-
|Gross heating value, MJ/kg||&nbsp;||align=center|43.50||align=center|25.92
|-
|[[Molecular mass]]||align=center|18||&nbsp;||&nbsp;
|-
|[[Specific gravity]]||&nbsp;||align=center|0.9626||&nbsp;
|-
|[[Carbon]]/[[hydrogen]] ratio by weight||&nbsp;||align=center|8.1||&nbsp;
|-
|weight % carbon||&nbsp;||&nbsp;||align=center|61.2
|-
|weight % hydrogen||&nbsp;||&nbsp;||align=center|4.3
|-
|weight % oxygen||&nbsp;||&nbsp;||align=center|7.4
|-
|weight % [[sulfur]]||&nbsp;||&nbsp;||align=center|3.9
|-
|weight % nitrogen||&nbsp;||&nbsp;||align=center|1.2
|-
|weight % [[Coal assay|ash]]||&nbsp;||&nbsp;||align=center|12.0
|-
|weight % [[Coal assay|moisture]]||&nbsp;||&nbsp;||align=center|10.0
|-
|'''Combustion air:'''||&nbsp;||&nbsp;||&nbsp;
|-
|Excess combustion air, %||align=center|12||align=center|15|| align=center|20
|-
|'''Wet combustion flue gas:'''||&nbsp;||&nbsp;||&nbsp;
|-
|Wet combustion flue gas, m³/GJ of fuel|| align=center|294.8||align=center|303.1||align=center|323.1
|-
|Molecular mass of wet combustion gas||align=center|27.7 ||align=center|29.0||align=center|29.5
|-
|'''Dry combustion flue gas:'''||&nbsp;||&nbsp;||&nbsp;
|-
|Dry combustion flue gas, m³/GJ of fuel|| align=center|241.6||align=center|269.3||align=center|293.6
|-
|Molecular mass of dry combustion gas||align=center|29.9 ||align=center|30.4||align=center|30.7
|-
|'''Notes:'''<br>(1) Gas amounts (m³) are at 0 °C and 1 atm<br>(2) Heating value = caloric value ||&nbsp;||&nbsp;||&nbsp;
|}
 
Given the amount of gas, oil or coal fuel burned in a combustion device, then the flue gas generation data (i.e., m³/GJ of fuel) in Table 1 provides a basis for estimating the amount of flue gas generated.


== Flue gas treatment ==
== Flue gas treatment ==
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In the United States, there is also a rapid deployment of technologies to remove mercury from flue gas - typically by [[adsorption]] on sorbents or by capture in inert solids as part of the flue gas desulfurization product.  
In the United States, there is also a rapid deployment of technologies to remove mercury from flue gas - typically by [[adsorption]] on sorbents or by capture in inert solids as part of the flue gas desulfurization product.  


Technologies for the removal and [[carbon capture and storage|capture]] of carbon dioxide  from flue gases are now under active research  and development as a means of reducing the emissions of so-called ''greenhouse gas''.
Technologies for the removal and [[carbon capture and storage|capture]] of carbon dioxide  from flue gases are now under active research  and development as a means of reducing the emissions of so-called ''greenhouse gas''.[[Category:Suggestion Bot Tag]]

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Flue gas is gas that exits to the atmosphere via a flue which may be a pipe, channel or chimney for conveying combustion product gases from a fireplace, oven, furnace, boiler or steam generator.

Flue gases are produced when coal, fuel oil, natural gas, wood or any other fuel is combusted in an industrial furnace or boiler, a steam generator in a fossil fuel power plant or other combustion sources.

Flue gas composition

Flue gas is usually composed of carbon dioxide (CO2) and water vapor as well as nitrogen and excess oxygen remaining from the intake combustion air. It may also contain a small percentage of air pollutants such as particulate matter, carbon monoxide, nitrogen oxides, sulfur oxides and mercury. Typically, more than two-thirds of the flue gas is nitrogen.

The table below provides the amounts of flue gas (on a dry basis as well as a wet basis) that are generated by burning a typical fuel gas, fuel oil or coal. The flue gas amounts were obtained by stoichiometric calculations using the indicated typical excess combustion air percentages:

(CC) Image: Milton Beychok

Given the amount of gas, oil or coal fuel burned in a combustion device, then the flue gas generation data (i.e., m³/GJ of fuel) in the above table provides a basis for estimating the amount of flue gas generated.

Flue gas treatment

At power plants, flue gas is often treated with a series of chemical processes and scrubbers, which remove pollutants. Electrostatic precipitators or fabric filters remove particulate matter and flue gas desulfurization captures the sulfur dioxide produced by burning fossil fuels, particularly coal.

Nitrogen oxides emissions are reduced either by modifications to the combustion process to prevent their formation, or by catalytic reaction with ammonia or urea. In either case, the aim is to produce nitrogen gas, rather than nitrogen oxides.

In the United States, there is also a rapid deployment of technologies to remove mercury from flue gas - typically by adsorption on sorbents or by capture in inert solids as part of the flue gas desulfurization product.

Technologies for the removal and capture of carbon dioxide from flue gases are now under active research and development as a means of reducing the emissions of so-called greenhouse gas.