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Matter (chemistry) for CZ

From the perspective of classical mechanics, or more specifically, Newtonian mechanics, chemists describe matter as anything that occupies space and has mass. That includes the subatomic particles that scientists can discern as having physical extension and mass, all the chemical elements, or elementary substances — "the substances from which everything tangible is made,"[1] — and all the substances chemical elements make up.

A minimal account of matter from the chemist´s Newtonian perspective requires discussion of the meanings of the terms 'thing' (or 'anything' or 'somthing' or 'everything'), 'mass', 'substance', 'chemical elements', and 'compounds'. This article uses the word 'object' generically to refer to something that occupies space and has mass.

Overview

Thing

When chemists define matter as anything (any thing) that occupies space and has mass they then do not define thing, presumably because the assume common knowledge of what thing means. Indeed, Linguists have discovered that the word 'thing' has a primary meaning indefinable using other words, and that the word occurs universally among the Earth's languages, though not universally pronounced as we pronounce it in English. Thing qualifies as one of approximately 60 additional universal Semantic primes, which though themselves indefinable serve as the basic set of words for defining all the other words in the language.[2]

Though indefinable in terms of other words, 'thing' still has meaning, a meaning a child learns from the way its elders use it, the origin of the word with a history of use going back to the deep-time beginnings of human speech. A child hears his parents frequently uttering 'thing' in reference to what we would call material objects: "This room has too many things in it."

Mass

Mass gives a measure of the quantity of matter in an object, expressed in kilograms (kg), a basic unit of the International System of Units (SI units). Three related measures of mass exist, referred to as 'inertial mass', 'passive gravitational mass', and 'active gravitational mass'. Physicists have established that the three measures give equivalent values despite their different conceptual bases.

Inertial mass relates to a quantity of matter's resistance to motion in response to an applied force, resistance measured in terms of the degree of acceleration it undergoes in response to the applied force. For a given force, an object with a larger mass accelerates more slowly than an object with a smaller mass. For an iron block to achieve the same acceleration of a wood block requires a larger force than that acting on the wood block. Newton´s Second Law of Motion formulates the mass: force equals mass times acceleration, F=ma, mass expressed in kilograms, force expressed in newtons, and acceleration expressed in meters per second per second. From the chemist´s Newtonian perspective, one cannot create mass or destroy it, consequent to the law of conservation of mass[3]

Passive gravitational mass gives a measure of the quantity of matter in virtue of its reference to the property of an object to react to a gravitational field, that is, to react by attraction to another mass generating a mass-attracting force, which Newton called gravitation. The magnitude of the force attracting the object measures its weight, which increases with larger attracting masses, but the object´s mass remains constant, in keeping with the unchanged quantity of matter in the object.

Active gravitational mass gives a measure of the quantity of matter in virtue of its reference to the property of an object to create a field of force surrounding it that attracts another object — its property of creating a gravitational field.

The equivalence of inertial mass and passive gravitational mass derives from Newton´s law of universal gravitation and the observation that different masses accelerate equally when let loose from the same height in a given gravitational field. The equivalence of passive and active gravitational mass derives both from Newton´s law of universal gravitation, Newton´s law of action and reaction,[4] and the observation that one cannot shield an object from the force of gravity. The derivations are the provenance of physics.[5]

Three points to note:

  1. An object´s mass gives a measure of the quantity of matter comprising the object;
  2. Objects have the same mass whether measured as inertial, passive, or gravitational mass;
  3. Einstein´s theories of special and general relativity modify the Newtonian concept of mass, which however give a useful measure of mass for most purposes in general chemistry.[3]

Substances

Chemistry conceptualizes matter as consisting of distinguishable types, referred to as 'substances'. [6] Examples of substances include such commonly recognized space-occupying masses as water in a glass container, the glass container itself, copper wire, a gem of pure diamond, and air enclosed in a balloon.

Different substances have different properties, either physical or chemical properties, depending on whether or not testing for the property involves the formation of another substance or substances.

All substances fall under two generic categories, 'pure substances' and 'mixtures'. Chemists classify as the quintessentially pure substances the [[Chemical elements}chemical elements]], types of matter composed solely of a single species of atoms, such as the copper atoms fashioned into copper wire, the carbon atoms comprising a diamond gem, or iron atoms in a chunk of purified iron. Ninety-four different species of atoms occur naturally on Earth, each collection, or sample, of which that consists solely of atoms of a single species constitutes a pure substance of the type of matter referred to as a chemical element, or elementary substance.

Compounds

The atoms of two or more different chemical elements potentially can bind to each other, in constant proportions, by any one of a variety of types of chemical bonds, forming in the process new types of pure substances referred to as 'compounds'. Water exemplifies a compound, composed of units of hydrogen and oxygen atoms tightly bonded, in the same proportion per bonded unit, in this case, two hydrogen atoms and one oxygen atom per unit of compound, expressed in chemical formula as H2O. Chemists have identified the bonds in a unit of the water compound as so-called covalent bonds, a type of bond that involves electron sharing between the hydrogen atoms and the oxygen atom, and refer to the unit as a molecule. Chemists express quantities of H2O with a variety of measures of mass, such as kilograms, a basic unit in the International System of Units (SI units), among six other basic units used to define all the myriad other units of quantity.

New test

By means of a novel mathematical analysis of the properties of the Periodic Table of Element, Albert Khazan reported in Progress in Physics an upper limit on the atomic number and mass of a chemical element:

The method of rectangular hyperbolas is developed for the first time, by which a means for estimating the upper bound of the Periodic Table is established in calculating that its last element has an atom mass of 411.663243 and an atomic number (the nuclear charge) of 155.[7]


Refs

  1. P.W. Atkins PW (1995). The Periodic Kingdom: A Journey into the Land of the Chemical Elements. Basic Books. ISBN 0-465-07265-0.  Full-Text (See page 3)
  2. Wierzbicka A. (1996) Semantics: Primes and Universals. Oxford University Press. ISBN 0198700024. Publisher’s website’s description of book Professor Wierzbicka’s faculty webpage Excepts from Chapters 1 and 2
  3. 3.0 3.1 Note: If one takes Einstein´s theory of special relativity into consideration, as a more accurate description of reality, mass increases as its velocity increases, hardly detectable as a rocket reaches Earth escape velocity, but hugely as the rocket approaches the speed of light. The theory of special relativity also predicts that mass need not obey the law of conservation of mass, because mass and energy exhibit two manifestations of the same thing, potentially enabling conversion of mass to energy, as in the nuclear reactions involved in generation of atomic energy, or energy to mass, as in the generation of hydrogen atoms from the energy released by the Big Bang that originated our universe.
  4. The law of action and reaction states that two interacting objects apply equal forces to one another, equal in magnitude and opposite in direction — as in two colliding billiard balls.
  5. Dunsby P. Mass in Newtonian Theory. Online course on relativity: Chapter 5.
    • An especially lucid, if somewhat technical, demonstration of the equivalances of the three concepts of mass.
  6. Hoffman J, Rosenkrantz G. (1996) Substance: It Nature and Existence. Routledge: London. ISBN 978-0-415-14032-4 (pbk). 240 pp. | Introduction & part of chapter 1 readable online free at publisher's website. | Full-Text online available with subscription to Questia Online Library | [http://bit.ly/2hIjsi Google Books Limited Preview (thru p54, with occasional pages missing.
  7. Khazan A. (2007) Upper Limit in the Periodic Table of Elements. Progress in Physics 1:38-41. | Download article PDF